Recovery of cyanide in gold leach waste solution by volat
Transcript
Recovery of cyanide in gold leach waste solution by volat
SETTORE VARIE Autori Gonen N., Kabasakal O. S., Ozdil G. Titolo "Recovery of cyanide in gold leach waste solution by volatilization and absorption" Rivista/Periodico Journal of Hazardous Materials, 113 (1 - 3) (2004) 233. Abstract In this study, the effects of pH, time and temperature in regeneration of cyanide in the leaching waste solution of gold production from disseminated gold ore by cyanidation process were investigated and the optimum conditions, consumptions and cyanide recovery values were determined. The sample of waste solution containing 156 mg/l free CN– and 358 mg/l total CN–, that was obtained from Gumushane - Mastra/Turkey disseminated gold ores by cyanidation and carbon - in - pulp (CIP) process under laboratory conditions was used in the experiments. Acidification with H2SO4, volatilization of hydrogen cyanide (HCN) with air stripping and absorption of HCN in a basic solution stages were applied and under optimum conditions, 100% of free cyanide and 48% of complex cyanide and consequently 70% of the total cyanide in the liquid phase of gold leach effluent are recovered. Keywords Gold leach; cyanide waste solution; cyanide removal; cyanide recovery; regeneration. Riassunto In questo studio sono analizzati gli effetti di pH, tempo e temperatura nel recupero dei cianuri dalle soluzioni di scarto per la produzione dell’oro a partire da minerali auriferi tramite processi di cianurazione. Vengono individuate le condizioni ottimali e determinate le quantità di cianuro recuperato. Con questo metodo sono stati recuperati il 100% del cianuro libero e il 48% di quello complessato con una resa totale del 70%. Dott. ssa Alessia Edifizi - Staff Orotech Fondazione G. Rumor - Centro Produttività Veneto (CPV) Via E. Fermi, 134 - 36100 Vicenza Tel. 0444 994708 Fax. 0444 994740 [email protected] www.orotech.it www.cpv.org