SDS - Do My Own Pest Control

Printed
18/01/11
Issued
22/11/2010
Revision
1.0 (22/11/2010)
SAFETY DATA SHEET
(According to Regulation EC No 453/2010)
1 – IDENTIFICATION OF THE MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product identifier
Trade name:
AXILO MIX 5
1.2 Relevant identified uses of the mixture and uses advised against
Relevant identified uses of the mixture:
Fertilizer
1.3 Details of the supplier of the safety data sheet: VALAGRO Spa
Zona Industriale
66041 ATESSA (CHIETI) ITALY
Tel. (+39) 0872 8811
Fax (+39) 0872 881382
Competent person responsible for the safety data
sheet:
1.4 Emergency telephone number:
E-mail: [email protected]
Tel. (+39) 02 66101029 (Centro Antiveleni Ospedale
Niguarda Milano)
Tel. (+39) 0872 8811 (Valagro Spa _ from Monday to
Friday from 8.30 to 13:00 and from 14:00 to 17.30 h)
2 – HAZARDS IDENTIFICATIONS
2.1 Classification of the mixture:
Classification according to Directive 1999/45/EC:
the product is not classified as hazardous according to Directive 99/45/EC
Most important adverse physicochemical, human health and environmental effects:
see sections from 9 to 12.
2.2 Label Elements
Hazard pictograms : none
Signal word:
none
Hazard statements: none
Precautionary statements: none
2.3 Other hazards
None
3 – COMPOSITION/INFORMATION ON INGREDIENTS
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Cod 11236_AXILO MIX 5
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Issued
Name
EINECS
CAS
Ethylendiaminete
traacetic acid,
copper disodic
complex
237-864-5
014025-151
22/11/2010
Classification Directive
67/548/EEC
Xn; R22
Revision
1.0 (22/11/2010)
Classification Regulation
(EC)1272/2008
Warning , Acute Tox. 4,
H302: Harmful if
swallowed.
Conc.
(%)
10
4 – FIRST AID MEASURES
4.1 Description of first aid measures
Routes of exposure:
- Inhalation: powder can irritate respiratory tract
-
Skin: Rinse the contaminated part with water and soap. Wash clothes before reuse.
-
Eye: Rinse with water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure
thorough rinsing. Seek medical advice
-
Ingestion: Rinse mouth, give water to drink. Seek medical advice
Advice:
None
4.2 Most important symptoms and effects, both acute and delayed
- Inhalation: N.A.
-
Skin: N.A.
-
Eye: N.A.
-
Ingestion: N.A.
4.3 Indication of any immediate medical attention and special treatment needed
N.A.
5 – FIREFIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media: vaporized water, foam, carbon dioxide (CO2).
Information on the appropriate extinguishing media: N.A.
Unsuitable extinguishing media: N.A.
Indications if extinguishing media are inappropriate for a particular situation involving the substance or
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mixture: N.A.
5.2 Special hazards arising from the substance:
nitrous and sulphur fumes can be released
5.3 Advice for firefighters:
Use self-contained respiratory equipment and fireproof clothing
6 – ACCIDENTAL RELEASE MEASURE
6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel: Keep away from the affected area people not involved in the emergency
intervention. Alert the responsible of the internal emergency.
For emergency responders: Wear protective clothes giving a total skin protection, latex gloves and safety
glasses. See also section 8
6.2 Environmental precautions:
If possible store into a clean container either to reuse or disposal . Avoid waterway and discharging contamination,
competent authority must be informed in case of waterway accidental contamination
6.3 Methods and material for containment and cleaning up:
Wash with plenty of water. Absorb with inert material (vermiculite). According to the contamination level store in
an authorized dump.
6.4 Reference to other sections:
referred to Sections 8 and 13
7 – HANDLING AND STORAGE
7.1. Precautions for safe handling
Operate in well-ventilated areas far from incompatible and reactive substances
7.2 Conditions for safe storage, including any incompatibilities
Storage in limited areas with containing device
7.3 Specific end use(s):
Always respect hygienic rules, do not drink neither eat. Avoid eye and skin contact. Use self-protective equipment.
Remove all contaminated clothing and wash them before reuse.
8 –EXPOSURE CONTROL/ PERSONAL PROTECTION
8.1 Control parameters
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Occupational exposure limit values:
Copper (Cu) exposure limits TWA 1 mg/m3 dust or mist
Iron (Fe) exposure limit TWA 1 mg/m3 soluble salts
Manganese (Mn) exposure limit TWA 0.2 mg/m3 inorganic compounds
ACGIH (2003): recommended limit – powder to be inhaled: TLV/TWA: 10 mg/m3
ACGIH (2003): recommended limit – breathable powder: TLV/TWA: 3 mg/m3
biological limit values: N.A.
DNEL: N.A.
PNEC: N.A.
Recommended monitoring procedures: N.A.
8.2 Exposure control
- Appropriate engineering controls: Ensure general or local air exchange through aspirators where fumes can be
released
- Individual protection measures, such as personal protective equipment:
Eye / face protection: Wear safety glasses according to the standard EN 166, don’t use contact lenses.
Skin protection:
-Hand protection: Wear latex gloves according to the standard EN 374.
-Other: Wear total skin protection clothes
Respiratory protection: Use anti-powder mask with P2 filters
- Environmental exposure controls: Keep product concentration under the established exposure limits
9 – PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearence (25° C):
Odour:
Odour threshold:
pH:
Yellow
green
microgranules
odourless
N.A.
N.A.
Melting point/freezing point:
N.A.
at 25 ° C
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Initial boiling point and boiling range:
N.A.
Flash point:
N.A.
Evaporation rate:
N.A.
Flammability (solid, gas):
N.A.
Upper/lower flammability or explosive limits:
N.A.
Vapour pressure:
N.A.
Vapour density:
N.A.
Relative density:
0,99
kg/dm3
100
g/l at 25°C
g/l at 25°C
Solubility:
- Solubility in water:
- Lipid solubility:
Partition coefficient:
n-octanol/water
Auto-ignition temperature:
N.A.
Decomposition temperature:
N.A.
Viscosity:
N.A.
Explosive properties:
N.A.
Oxidising properties:
N.A.
9.2 Other information
pH water solution 1%
Conductivity
4.5
0.55
N.A.
at 25° C
(1‰) mS/cm 18 °C
10 – STABILITY AND REACTIVITY
10.1 Reactivity:
Heating at high temperature (250-300 °C) ; humid and unventilated places
10.2 Chemical stability:
N.A.
10.3 Possibility of hazardous reactions:
in case of fire NOx; CO are released
10.4 Conditions to avoid:
N.A.
10.5 Incompatible materials:
N.A.
10.6 Hazardous decomposition products:
N.A.
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11 – TOXICOLOGICAL INFORMATION
Toxicological (health) effects caused by exposure to the mixture: see also sections 2 and 4.
11.1 Information on toxicological effects
-
acute toxicity: LD50 oral,rat, >1750 mg/Kg for copper EDTA
-
irritation: the prolonged skin contact may cause irritation and itches, direct eye contact may cause
irritation
-
corrosivity: N.A.
-
sensitisation: N.A.
-
repeated dose toxicity: N.A.
-
Carcinogenicity: N.A.
-
mutagenicity: N.A.
-
toxicity for reproduction: N.A.
12 – ECOLOGICAL INFORMATION
Use according to good working rules, avoid to dispose of the product in the environment (see sections 6,
7, 13,14 e 15).
12.1 Toxicity:
Aquatic: (for Copper EDTA)
Fish (96 hoursLC50) >100 mg/l
Daphna magna (24 hours EC50) >500 mg/l
Algae, the use of EDTA invalidates tests conditions of algae growth inhibition
12.2 Persistence and degradability:
N.A.
12.3 Bioaccumulative potential:
N.A.
12.4 Mobility in soil:
N.A.
12.5 Results of PBT and vPvB assessment
N.A.
12.6 Other adverse effects
N.A.
13 – DISPOSAL CONSIDERATIONS
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13.1 Waste treatment methods
Recover the product, if possible, or send to the incineration and disposal system.
Avoid waterway and discharging contamination.
Follow the local and national disposition in force
14 – TRANSPORT INFORMATION
Not dangerous product within the meaning of transport regulations
15 – REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance:
Council Directive 67/548/EEC (Classification, packaging and labelling of dangerous substances) and subsequent
amendments. Council Directive 1999/45/EC (Classification, packaging and labelling of dangerous preparations)
and subsequent amendments. Commission Directive 98/24/EC (Protection of the health and safety of workers from
the risk related to chemical agent). Commission Directive 2000/39/EC (Occupational exposure limit values).
Regulation (EC) No 1907/2006 (REACH).Regulation (EC) No 1272/2008 (CLP) (Annex VI). Regulation (EC) No
790/2009 (Annex IV, Annex V).
15.2. Chemical safety assessment:
16 – OTHER INFORMATION
This MSDS was revised to get it compliant to regulation 453/2010 and cancels and replaces any preceding release.
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely
to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific
use intended.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the
European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
ACGIH - Threshold Limit Values - 2004 edition
ESIS
Xn: harmful
R22: Harmful if swallowed
Acronyms used in the safety data sheet:
ADN: Accord europeen relative au transport international des marchandises dangereuses par voies de navigation
interieures (accordo europeo relativo al trasporto internazionale delle merci pericolose per vie navigabili interne)
ADR: Accord europeen relative au transport International des marchandises dangereuses par route (accordo
europeo relativo al trasporto internazionale delle merci pericolose su strada)
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ACGIH: American Conference of Governmental Industrial Hygienist
BOD5: Biological Oxygen Demand (domanda biochimica di ossigeno)
COD: Chemical Oxygen Demand (domanda chimica di ossigeno)
CL50: Lethal concentration 50 (Concentrazione Letale per il 50% degli individui)
CLP: Classification, Labelling and Packaging (Classificazione, Etichettatura e Imballaggio)
CSR: Rapporto sulla sicurezza chimica (Chemical Safety Report)
DL 50: Lethal Dose 50 (Dose letale per il 50% degli individui)
DNEL : Derived No effect level (livello derivato senza effetto)
IARC: International Agency for Research on Cancer (Ente internazionale per la ricerca sul cancro)
IATA: International air transport association (associazione internazionale del trasporto Aereo)
ICAO: International Civil aviation Organization (Organizzazione Internazionale dell’Aviazione Civile)
Codice IMDG: International Maritime Dangerous Goods code (Codice sul regolamento del trasporto marittimo)
PBT: Persistent, bioaccumulative and toxic (sostanze persistenti, bioaccumulabili e tossiche)
PNEC: Predicted No Effect Concentration (concentrazione prevedibile priva di effetti)
RID: Reglement concernent le transport International ferroviarie des marchandises dangereuses (Regolamento
concernente il trasporto Internazionale ferroviario delle merci Pericolose)
STEL: short term exposure limit (limite di esposizione a breve termine)
TLV: threshold limit value (soglia di valore limite)
TWA: Time Weighted Average (media ponderata nel tempo)
UE: European Union (Unione europea)
vPvB: Very persistent very bioaccumulative (sostanze molto persistenti e molto bioaccumulabili)
N.A. : not available
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