Xn - sol.it

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Xn - sol.it

Page : 1 / 6
SAFETY DATA SHEET
Revised edition no : 1
Date : 18 / 4 / 2008
Supersedes : 0 / 0 / 0
MISCELA CONTENENTE 0.5-1% DI SOLFURO DI
CARBONIO (P)
799
ê
X
Xn : Harmful
“M
M
«
Warning
Identification of the product
Globally Harmonized System of Classification and Labelling of Chemicals (GHS)
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006
Hazard Class and Category Code
Regulation EC 1272/2008 (CLP)
• Physical hazards
• Health hazards
: Gases under pressure - Compressed gas - Warning (H280)
: Specific Target Organ Toxicity - Repeated exposure - Category 2 - Warning (H373)
Labelling Regulation EC 1272/2008 (CLP)
• Hazard pictograms
• Signal word
• Hazard statements
“ M
M
«
: Warning
: H373 : May cause damage to organs through prolonged or repeated exposure.
H280 : Contains gas under pressure; may explode if heated.
1 Identification of the substance/mixture and of the company/undertaking
Trade name
SDS Nr
Use
Company identification
Emergency telephone number
:
:
:
:
MISCELA CONTENENTE 0.5-1% DI SOLFURO DI CARBONIO (P)
799
Industrial and professional. Perform risk assessment prior to use.
SOL SpA
Via G. Borgazzi 27
20900 MONZA Italia
Tel : +39.039.23.961 | Fax : +39.039.23.96.420
email: [email protected] | http://www.sol.it/msds2/msds.asp
: +39.089.301.810
SOL SpA
Via G. Borgazzi 27 20900 MONZA Italia
Tel : +39.039.23.961 | Fax : +39.039.23.96.420
In case of emergency : +39.089.301.810
Page : 2 / 6
SAFETY DATA SHEET
Date : 18 / 4 / 2008
CARBONIO (P)
799
3 Hazards identification
Classification of the substance or mixture
Classification EC 67/548 or EC 1999/ : Xn; 48/20
45
Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s)
X
ê
: Xn : Harmful
: R48/20 : Harmful : danger of serious damage to health by prolonged exposure
through inhalation.
: S9 : Keep container in a well-ventilated place.
S23 : Do not breathe the gas.
: In high concentrations may cause asphyxiation.
Compressed gas.
R Phrase(s)
S Phrase(s)
Hazards identification
Other hazards
: None.
Other hazards
2 Composition/information on ingredients
: Mixture.
: This product is hazardous.
Substance / Mixture
Components
Substance name
Carbon disulphide
:
Contents
Between 0.5 and 1 %
CAS No
75-15-0
EC No
200-843-6
Index No
006-003-00-3
Registration no Classification
F; R11
----Repr. Cat. 3; R62
Repr. Cat. 3; R63
T; R48/23
Xi; R36/38
Full text of R-phrases see chapter 16
Note 1: Listed in Annex IV / V REACH, exempted from registration.
Note 2: Registration deadline not expired.
4 First aid measures
First aid measures
- Inhalation
- Skin/eye contact
- Ingestion
: Remove victim to uncontaminated area wearing self contained breathing
apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if
breathing stopped.
: Not expected to present a significant skin hazard under anticipated conditions of
normal use.
: Ingestion is not considered a potential route of exposure.
SOL SpA
Tel : +39.039.23.961 | Fax : +39.039.23.96.420
Page : 3 / 6
SAFETY DATA SHEET
Date : 18 / 4 / 2008
CARBONIO (P)
799
5 Fire-fighting measures
- Specific hazards
- Hazardous combustion products
: Exposure to fire may cause containers to rupture/explode.
: Toxic gases.
Extinguishing media
: All known extinguishants can be used.
: None.
: If possible, stop flow of product.
Move away from the container and cool with water from a protected position.
- Special protective equipment for fire : In confined space use self-contained breathing apparatus.
fighters
- Suitable extinguishing media
- Unsuitable extinguishing media
- Specific methods
6 Accidental release measures
Environmental precautions
: Try to stop release.
Prevent from entering sewers, basements and workpits, or any place where its
accumulation can be dangerous.
7 Handling and storage
: Open valve slowly to avoid pressure shock.
Suck back of water into the container must be prevented.
Do not allow backfeed into the container.
Use only properly specified equipment which is suitable for this product, its supply
pressure and temperature. Contact your gas supplier if in doubt.
Conditions for safe storage, including : Keep container below 50°C in a well ventilated place.
any incompatibilities
: Not established.
Specific end use(s)
Precautions for safe handling
8 Exposure controls/personal protection
- Respiratory protection
- Hand protection
- Skin protection
- Eye protection
- Occupational Exposure Limits
Recommended monitoring
procedures
: No special respiratory protection equipment is recommended under normal
conditions of use with adequate ventilation.
: Wear suitable gloves.
: Skin protection appropriate to the conditions of use should be provided.
: Even though no eye contact is expected under reasonable normal conditions of
use, appropriate eye protection should be worn when handling this material.
: Carbon disulphide : TLV© -TWA [ppm] : 10
: Ensure adequate ventilation.
Exposure controls
9 Physical and chemical properties
Physical state at 20 °C
Colour
: Compressed gas.
: Colourless.
SOL SpA
Tel : +39.039.23.961 | Fax : +39.039.23.96.420
Page : 4 / 6
SAFETY DATA SHEET
Date : 18 / 4 / 2008
CARBONIO (P)
799
9 Physical and chemical properties (continued)
Odour
Relative density, gas (air=1)
Other data
: Light.
: Heavier than air.
: Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or
below ground level.
10 Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
: May react violently with halogenated hydrocarbons.
Reacts violently with oxidizing substances.
: Stable under normal conditions.
: Reacts violently with oxidizing substances.
May react violently with halogenated hydrocarbons.
: Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
: Strong oxidizers. Halogens. Alkaline earth metals
: Toxic gases.
11 Toxicological information
Inhalation
Dermal
Ocular
Ingestion
Rat inhalation LC50 [ppm/4h]
:
:
:
:
:
Irritating to eyes, respiratory system and skin.
Ingestion is not considered a potential route of exposure.
• Carbon disulphide : 850
12 Ecological information
Ecological effects information
Environmental precautions
Effect on ozone layer
Bioaccumulative potential
Persistence and degradability
: Prevent from entering sewers, basements and workpits, or any place where its
accumulation can be dangerous.
: None.
: Not established.
: Not established.
13 Disposal considerations
General
Disposal method
: Do not discharge into any place where its accumulation could be dangerous.
Contact supplier if guidance is required.
: Consult supplier for specific recommendations.
Consult supplier for specific recommendations.
14 Transport information
- UN number
- H.I. nr
: 1956
: 20
SOL SpA
Tel : +39.039.23.961 | Fax : +39.039.23.96.420
Page : 5 / 6
SAFETY DATA SHEET
Date : 18 / 4 / 2008
CARBONIO (P)
799
14 Transport information (continued)
Land transport
- UN proper shipping name
ADR/RID
- Transport hazard class(es)
- ADR/RID Classification code
: COMPRESSED GAS, N.O.S. (Argon, Carbon disulphide)
: 2
: 1A
Sea transport
IMO-IMDG code
- IMO Packing group
- IMDG-Marine pollution
: P200
: NO
Air transport
ICAO/IATA
Avoid transport on vehicles where the load space is not separated from the driver's compartment.
Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an
emergency.
Before transporting product containers :
- Ensure that containers are firmly secured.
- Ensure cylinder valve is closed and not leaking.
- Ensure valve outlet cap nut or plug (where provided) is correctly fitted.
- Ensure valve protection device (where provided) is correctly fitted.
- Ensure there is adequate ventilation.
- Compliance with applicable regulations.
16 Other information
Asphyxiant in high concentrations.
Keep container in a well-ventilated place.
Do not breathe the gas.
The hazard of asphyxiation is often overlooked and must be stressed during operator training.
Receptacle under pressure.
: R11 : Highly flammable.
List of full text of R-phrases in
R36/38 : Irritating to eyes and skin.
section 3.
R48/23 : Toxic : danger of serious damage to health by prolonged exposure
through inhalation.
R62 : Possible risk of impaired fertility.
R63 : Possible risk of harm to the unborn child.
: Before using this product in any new process or experiment, a thorough material
DISCLAIMER OF LIABILITY
compatibility and safety study should be carried out.
Details given in this document are believed to be correct at the time of going to
press. Whilst proper care has been taken in the preparation of this document, no
liability for injury or damage resulting from its use can be accepted.
This Safety Data Sheet has been established in accordance with the applicable European Directives and applies to all
countries that have translated the Directives in their national laws.
The contents and format of this SDS are in accordance with EC Commission Directive 2001/58/EC.
SOL SpA
Tel : +39.039.23.961 | Fax : +39.039.23.96.420
Page : 6 / 6
SAFETY DATA SHEET
Date : 18 / 4 / 2008
CARBONIO (P)
799
End of document
SOL SpA
Tel : +39.039.23.961 | Fax : +39.039.23.96.420

Xn - sol.it

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