a recent list

Full list of the publications of Luigi Vaccaro
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S. Santoro, S. Kozhushkov, L. Ackermann*, L. Vaccaro*. Heterogeneous Catalytic
Approaches in C–H Activation Reactions. Green Chem., 2016, DOI: 10.1039/C6GC00385K.
G. Strappaveccia, S. Ziarelli, F. Pizzo, L. Vaccaro*. PS-BEMP as a Heterogeneous Base
Catalyst for Phospha-Michael Addition of α,β-Unsaturated Ketones. Org. Biomol. Chem.
2016, DOI: 10.1039/C6OB00242K.
M. P. Bracciale, A. Broggi*, E. Bartollini, F. Sbardella, M. Poldi, A. Marrocchi*, M. L.
Santarelli, L. Vaccaro*. Preparation and characterization of cross-linked polymer supports
for catalysts immobilization. Int. J. Eng. Res. Sci. 2016, 2, 166‒189.
E. Ballerini, R. Maggi, F. Pizzo, D. Gelman, O. Piermatti, L. Vaccaro*. An efficient and waste
minimized one-pot procedure for the preparation of γ-amino alcohols starting from α,βunsaturated ketones in flow. Org. Process Res. Dev. 2016, 20, 474–479.
A. Marrocchi*, A. Facchetti, C. Petrucci, D. Lanari, L. Vaccaro*. Current synthetic tools for
the preparation of semiconducting polymers. Energy Environ. Sci., 2016, 9 , 763‒786.
M. Tassi, E. Bartollini, P. Adriaensens, L. Bianchi, B. Barkakaty, R. Carleer, J. Chen, D. K.
Hensley, A. Marrocchi, L. Vaccaro*. Synthesis, characterization and catalytic activity of
novel large network polystyrene-immobilized organic bases. RSC Advances 2015, 5,
107200-107208.
A. Marrocchi, P. Adriaensens, E. Bartollini, B. Barkakati, R. Carleer, J. Chen, D. K. Hensley,
C. Petrucci, M. Tassi, L. Vaccaro*. Novel cross-linked polystyrenes with large space network
as tailor-made catalyst supports for sustainable media. Eur. Pol. J. 2015, 75, 391–401.
M. Nocchetti, C. Petrucci, F. Costantino, O. Piermatti, L. Vaccaro*. Highly Active Pd
Nanoparticles Supported on Zirconium Carboxy-aminophosphonate Nanosheets as Novel
Catalyst for Sustainable Applications. Chem. Commun. 2015, 51, 15990-15993. highlighted
in Synfacts 2016, 12 (01), 0105-0105.
Reductive Amination of Phenols, a Simple Process To Access Substituted
Cyclohexylamines. 2015, Org. Lett. 2015, 17, 3990−3993.
L. A. Bivona, F. Giacalone, L. Vaccaro, C. Aprile, M. Gruttadauria. Cross-Linked Thiazolidine
Network as Support for Palladium: A New Catalyst for Suzuki and Heck Reactions.
ChemCatChem 2015, 7, 2526–2533.
S. Musa, A. Ghosh, L. Vaccaro, L. Ackermann, D. Gelman,. Efficient E-Selective Transfer
Semihydrogenation of Alkynes by Means of Ligand-Metal Cooperating Ruthenium Catalyst.
Adv. Synth. Catal. 2015, 357, 2351 –2357.
L. Bianchi, E. Ballerini, M. Curini, D. Lanari, A. Marrocchi, C. Oldani, L. Vaccaro*. Aquivion
PFSA as a Novel Solid and Reusable Acid Catalyst in the Synthesis of 2-Pyrrolidin-2-ones in
Flow. ACS Sus. Chem. Eng. 2015, 3, 1873−1880.
E. Ballerini, M. Curini, D. Gelman, D. Lanari, O. Piermatti, F. Pizzo, S. Santoro, L. Vaccaro*.
waste minimized multistep preparation in flow of β‑amino acids starting from α,β-Unsaturated
carboxylic acids. ACS Sus. Chem. Eng. 2015, 3, 1221-1226.
C. Petrucci, L. Vaccaro*. Prodotti chimici dalle biomasse: il γ-valerolattone, alternativa
sostenibile ai solventi dipolari aprotici in reazioni di cross-coupling. La Chimica e l’Industria
(ISSN 0009-4315)- 2015, 97, 52-58. DOI: http://dx.medra.org/10.17374/CI.2015.97.1.52.
C. Petrucci, M. Cappelletti, O. Piermatti, M. Nocchetti, M. Pica, F. Pizzo, L. Vaccaro*.
Immobilized palladium nanoparticles on potassium zirconiumphosphate as an efficient
recoverable heterogeneous catalyst for aclean Heck reaction in flow. J. Mol. Catal. A:
Chemical 2015, 401, 27–34.
G. Strappaveccia, L. Luciani, E. Bartollini, A. Marrocchi, F. Pizzo, L. Vaccaro*. Searching for
a biomass derived safer dipolar aprotic medium. γ-Valerolactone as an alternative medium
for a greener Sonogashira reaction. Green Chem, 2015, 17, 1071–1076.
J. Andraos, E. Ballerini, L. Vaccaro*. A comparative approach to the most sustainable
protocol for the β-azidation of α,β-unsaturated ketones and acids. Green Chem. 2015, 17
913–925.
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G. Strappaveccia, E. Ismalaj, C. Petrucci, D. Lanari, A. Marrocchi, M. Drees, A. Facchetti, L.
Vaccaro*. Biomass-derived safe medium to replace toxic dipolar solvents and access
cleaner Heck coupling reactions. Green Chem. 2015, 17, 365-372.
C. Petrucci, G. Strappaveccia, F. Giacalone, M. Gruttadauria, F. Pizzo, L. Vaccaro*. An Efactor minimized protocol for a sustainable and efficient Heck reaction in flow. ACS Sus.
Chem. 2014, 2, 2813−2819.
S. Bonollo, A. Zarei Ahmady, C. Petrucci, A. Marrocchi, F. Pizzo, L. Vaccaro*. A Catalytic
Approach to the Metal-Free Reaction of Epoxides with Ketene Silyl Acetals for Accessing
γ‑Lactones, Org. Lett. 2014, 16, 5721-5723.
E. Ismalaj, G. Strappaveccia, E. Ballerini, F. Elisei, O. Piermatti, D. Gelman, L. Vaccaro*. γValerolactone as a renewable dipolar aprotic solvent deriving from biomass degradation for
the Hiyama reaction. ACS Sus. Chem. Eng. 2014, 2, 2461-2464.
L. Vaccaro*, G. Strappaveccia, D. Lanari, A. Marrocchi. Flow approaches towards
sustainability. Green Chem. 2014, 16, 3680-3704.
E. Ballerini, F. Pizzo, L. Vaccaro*. Waste minimized synthesis of γ-nitroketones. Proven
Green Syntheses, Volume 1, CRC Press. 2014, pp. 109-119.
E. Ismalaj, F. Pizzo, L. Vaccaro*. Environmentally-friendly synthesis of norstatines in water.
Proven Green Syntheses, Volume 1, CRC Press. 2014, pp. 191-202.
C. Pavia, F. Giacalone, L. A. Bivona, A. M. P. Salvo, C. Petrucci, G. Strappaveccia, L.
Vaccaro, C. Aprile, M. Gruttadauria. Evidences of release and catch mechanism in the Heck
reactioncatalyzed by palladium immobilized on highlycross-linked-supported imidazolium
salts. J. Mol Catal. A: Chem. 2014, 387, 57–62.
A. Broggi, I. Tomasi, L. Bianchi, A. Marrocchi, L. Vaccaro. Small Molecular Aryl Acetykenes:
chemically taioloring high-efficiency organic semicoductors for solar cells and field-effect
transistors. ChemPlusChem 2014, 79, 486-507.
T. Angelini, S. Bonollo, E. Ballerini, D. Lanari, R. Maggi, G. Sartori, L. Vaccaro*. Multistep
flow procedure for the waste-minimized preparation of N-Boc-β-amino ketones. J. Flow
Chem. 2014, 4, 40-43.
M. Angeloni, O. Piermatti, F. Pizzo, L. Vaccaro*. Synthesis of new supported L-proline on
zirconium phosphonates as effective catalysts for direct asymmetric aldol addition. Eur. J.
Org. Chem. 2014, 1716-1726. highlighted in SYNFACTS 2014, 650.
A. Marrocchi, M. Gruttadauria, L. Vaccaro*. Nuovi strumenti sintetici per la sintesi sostenibile
di semiconduttori organici. La chimica e l’Industria 2013, 115-119.
M. Alonzi, M. P. Bracciale, A. Broggi, D. Lanari, A. Marrocchi, M. L. Santarelli, L. Vaccaro*.
Synthesis and characterization of novel polystyrene-supported TBD catalysts and their use in
the Michael addition for the synthesis of Warfarin and its analogues. J. Catal. 2014, 309,
260–267.
O. Cohen, O. Grossman, L. Vaccaro, D. Gelman. Synthesis of chiral nonracemic PC(sp3)P
pincer ligands. J. Organom. Chem. 2014, 750, 13-16.
C. G. Piscopo, G. Sartori, J. A. Mayoral, D. Lanari, L. Vaccaro, R. Maggi. Study on the
influence of a sustainable medium for the design of multistep processes: three-component
synthesis of 2-nitroamines. Synlett 2013, 24, 2596-2600.
M. Alonzi, D. Lanari, A. Marrocchi, L. Vaccaro*. Synthesis of polymeric semiconductors by
surface-initiated approach. RSC Advances. invited review article, 2013, 3, 23909- 23923.
E. Ballerini, P. Crotti, I. Frau, D. Lanari, F. Pizzo, L. Vaccaro*. A waste-minimized protocol
for the preparation of 1,2-azido alcohols and 1,2-amino alcohols. Green Chem. 2013, 15,
2394-2400. HOT PAPER, cover journal accepted for publication.
S. Musa, S. Fronton, L. Vaccaro, D. Gelman. Bifunctional Ruthenium(II) PCP Pincer
Complexes and Their Catalytic Activity in Acceptorless Dehydrogenative Reactions.
Organometallics 2013, 32, 3069−3073.
C. Pavia, E. Ballerini, L. A. Bivona, F. Giacalone, C. Aprile, L. Vaccaro*, M. Gruttadauria.
Palladium Supported on Cross-Linked Imidazolium Network on Silica as Highly Sustainable
Catalysts for the Suzuki Reaction under Flow Conditions. Adv. Synth. Catal., 2013, 355,
2007 – 2018.
T. Angelini, S. Bonollo, D. Lanari, F. Pizzo, L. Vaccaro. E-Factor minimized
hydrophosphonylation of aldehydes catalyzed by polystyryl-BEMP under solvent-free
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conditions. Org. Biomol. Chem., 2013, 11, 5042–5046. highlighted in SYNFACTS 2013,
1133.
E. Bartollini, M. Seri, S. Tortorella, A. Facchetti, T. J. Marks, A. Marrocchi, L. Vaccaro*.
Sustainable synthetic approach to p-conjugated arylacetylenic semiconductors for bulk
heterojunction solar cells. RSC Adv., 2013, 3, 9288–9295.
S. Bonollo, D. Lanari, L. Vaccaro*. (R,R)-6,6-Bis(1-hydroxy-2,2-dimethylpropyl)-2,2bipyridine, Encyclopedia of Reagents for Organic Synthesis, Wiley 2012.
G. Strappaveccia, D. Lanari, D. Gelman, F. Pizzo, O. Rosati, M. Curini, L. Vaccaro*. Efficient
synthesis of cyanohydrin trimethylsilyl ethers via 1,2-chemoselective cyanosilylation of
carbonyls. Green Chem. 2013, 199–204.
A. Marrocchi, D. Lanari, A. Facchetti, L. Vaccaro*. Poly(3-hexylthiophene): synthetic
methodologies and properties in bulk heterojunction solar cells. Energy Env. Sci. 2012, 5,
8457-8474.
S. Gabrielli, A. Palmieri, D. Panmand, D. Lanari, L. Vaccaro, R. Ballini. β-Nitroacrylates as
Key Starting Materials for the One-Pot Synthesis of Densely Functionalized PentaSubstituted Anilines. Tetrahedron, 2012, 68, 8231-8235.
T. Angelini, S. Bonollo, D. Lanari, F. Pizzo, L. Vaccaro*. A Protocol for Accessing the
β‑Azidation of α,β-Unsaturated Carboxylic Acids. Org. Lett. 2012, 14, 4610-4613.
D. Lanari, O. Piermatti, F. Pizzo, L. Vaccaro*. Cu(OTf)2/SDS-catalyzed preparation of 1,2diphenyl-2,3-dihydro-4-pyridones in acidic aqueous medium. Synthesis 2012, 2181 2184.
D. Lanari, O. Piermatti, F. Pizzo, L. Vaccaro*. Green Solvents I: Properties and Applications
in Chemistry, A. Mohammad and Inamuddin (eds.), Springer, 2012.
L. Vaccaro. New synthetic tools for the definition of sustainable continuous flow reactors. La
chimica e l’Industria 2012, 64-68.
P. Wolfer, M. L. Santarelli, L. Vaccaro, A. Broggi, D. Lanari, L. Yu, T. D. Anthopoulos, P.
Smith, N. Stingelin,* A. Marrocchi*. Semiconducting Arylacetylene:Insulating Polymer Blends
for Organic-Based Electronic Devices. Mater. Res. Soc. Symp. Proc. 2012, 140, u08-06
ISSN 0272-9172.
A. Facchetti,* L. Vaccaro, A. Marrocchi. Semiconducting polymers prepared by direct
arylation polycondensation. Angew. Chem. Int. Ed. 2012, 51, 3520 – 3523.
T. Angelini, D. Lanari, R. Maggi, F. Pizzo, G. Sartori, L. Vaccaro*. Preparation and use of
polystyryl-DABCOF2 : an efficient recoverable and reusable catalyst for β-azidation of α,βunsaturated ketones in water. Adv. Synth. Catal. 2012, 354, 908–916. highlighted in
SYNFACTS 2012, 689.
S. Bonollo, D. Lanari*, L. Vaccaro*. [2]Catenanes on surfaces as candidates for
nanoelectronic devices. Curr. Org. Synth. 2012, 9, 188-198. Invited, special issue on
"Functional π-electron systems. Organic synthesis for efficient plastic electronics.
A. Marrocchi,* I. Tomasi, and L. Vaccaro*. Organic small-molecules for photonic and
electronics from the [2.2]paracyclophane scaffold. Isr. J. Chem. 2012, 52, 41–52. Invited,
special issue on "Cyclophanes”.
S. Bonollo, D. Lanari, J. M. Longo, and L. Vaccaro*. E-factor minimized protocols for the
polystyryl-BEMP catalyzed conjugate additions of various nucleophiles to α,β-unsaturated
carbonyl compounds. Green Chem. 2012, 14, 164-1695.
S. Bonollo, D. Lanari*, T. Angelini, F. Pizzo, A. Marrocchi, and L. Vaccaro*. Rasta resin as
support for TBD in base-catalyzed organic processes. J. Catal. 2012, 285, 216-222.
L. Vaccaro. Processi in flusso continuo per lo sviluppo di una chimica organica sostenibile.
La chimica e l’Industria 2011, 121-127.
D. Lanari*, R. Ballini, S. Bonollo, A. Palmieri, F. Pizzo and L. Vaccaro*. JandaJel as a
polymeric support to improve the catalytic efficiency of immobilized-1,5,7triazabicyclo[4.4.0]dec-5-ene (TBD) under solvent-free conditions. Green Chem. 2011, 13,
3181-3186.
R. Maggi*, D. Lanari, C. Oro, G. Sartori, and L. Vaccaro*. Heterogeneous
bisoxazoline/copper complex: a green catalyst for the enantioselective reaction of
nitromethane with substituted benzaldehydes. Eur. J. Org. Chem. 2011, 5551–5554.
P. Wolfer, M. L. Santarelli, L. Vaccaro, L. Yu, T. D. Anthopoulos, P. Smith, N. Stingelin,* A.
Marrocchi*. Influence of molecular architecture and processing on properties of
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semiconducting arylacetylene: Insulating poly(vinylidene fluoride) blends. Org. Electron.
2011, 12, 1886–1892.
D. Lanari, F. Montanari, F. Marmottini, O. Piermatti*, M. Orrù, and L. Vaccaro. New
zirconium hydrogen phosphate alkyl and/or aryl phosphonates with high surface area as
heterogeneous Brønsted acid catalysts for aza-Diels–Alder reaction in aqueous medium. J.
Catal. 2011, 277 80–87.
A. Palmieri,* S. Gabrielli, D. Lanari, and L. Vaccaro. A new one-pot synthesis of
polysubstituted indoles from pyrroles and β-nitroacrylates. Adv. Synth. Catal. 2011, 353,
1425–1428.
D. Lanari*, R. Ballini, A. Palmieri, F. Pizzo, and L. Vaccaro*. Diastereoselective three-step
route to o-(6-nitrocyclohex-3-en-1-yl)phenol and tetrahydro-6h-benzo[c]chromen-6-ol
derivatives from salicylaldehydes. Eur. J. Org. Chem. 2011, 2874–2884.
S. Bonollo, D. Lanari, A. Marrocchi and L. Vaccaro*. Stereoselective ring-opening reactions
of epoxides in water. Curr. Org. Synth. 2011, 8, 319-329. Invited, special issue on “Watermediated Organic Reactions”.
S. Bonollo, D. Lanari, and L. Vaccaro*. Ring-opening of epoxides in water. Eur. J. Org.
2011, 2587–2598. Invited account on personal scientific achievements.
S. Bonollo, D. Lanari, F. Pizzo, and L. Vaccaro*. Sc(III)-catalyzed enantioselective addition
of thiols to α,β-unsaturated ketones in neutral water. Org.Lett. 2011, 13, 2150–2152.
highlighted in SYNFACTS 2011, 811.
S. Calogero, D. Lanari, M. Orrù, O. Piermatti*, F. Pizzo, and L. Vaccaro. Supported L-proline
on zirconium phosphates methyl and/or phenyl phosphonates as heterogeneous
organocatalysts for direct asymmetric aldol addition. J. Catal. 2011, 277 112–119.
A. Zvagulis, S. Bonollo, D. Lanari, F. Pizzo, and L. Vaccaro*. 2-tert-Butylimino-2diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine supported on polystyrene (PSBEMP) as an efficient recoverable and reusable catalyst for the phenolysis of epoxides under
solvent-free conditions. Adv. Synth. Catal. 2010, 352, 2489–2496.
F. Fringuelli, D. Lanari, F. Pizzo and L. Vaccaro*. An E-factor minimized protocol for the
preparation of methyl β-hydroxy esters. Green Chem., 2010, 12, 1301–1305. HOT PAPER.
T. Angelini, F. Fringuelli, D. Lanari, F. Pizzo, L. Vaccaro. A catalytic approach to the basepromoted reaction of epoxides with activated methylenes. Tetrahedron Lett. 2010, 50, 15661569.
F. Fringuelli, O. Piermatti, F. Pizzo, and L. Vaccaro. Diels-Alder reactions, Science of
Synthesis 2009 47b, 561-736. Invited.
F. Fringuelli, D. Lanari, F. Pizzo, L. Vaccaro. Solid-Supported Ammonium Fluorides in
Organic Synthesis. Curr. Org. Synth. 2009, 6, 203-218.
L. Vaccaro*, D. Lanari. Introduction and Transformation of Functional Groups in XXXIV
School on Organic Synthesis "A. Corbella", 2009, 317-343, ISBN 9788886208581.
Castrica L., Fringuelli F., Pizzo F., L. Vaccaro, Enantioselective Michael Addition of Dimethyl
Malonate to (E)-ß-Nitrostyrenes Catalyzed by Cinchona Alkaloids under Solvent-Free
Condition. Lett. Org. Chem., 2008, 5, 602-606.
F. Fringuelli, D. Lanari, F. Pizzo, L. Vaccaro*. Amberlite IRA900F as a Solid Fluoride Source
for a Variety of Organic Transformations under Solvent-Free Conditions. Eur. J. Org. Chem.
2008, 3928-3932. highlighted in SYNFACTS 2008, 1233.
Bonollo S., Fringuelli F., Pizzo F., L. Vaccaro, Zn(II)-Catalyzed Desymmetrization of mesoEpoxides by Aromatic Amines in Water. Synlett, 2008, 1574-1578.
R. Ballini, L. Barboni, L. Castrica, F. Fringuelli, D. Lanari, F. Pizzo, L. Vaccaro* PolystyrylBEMP as an Efficient Recyclable Catalyst for the Nucleophilic Addition of Nitroalkanes to α,βUnsaturated Carbonyl Compounds under Solvent-Free Conditions. Adv. Synth. Catal. 2008,
350, 1218-1224. highlighted in SYNFACTS 2008, 886.
R. Ballini, G. Bosica, A. Palmieri, F. Pizzo, L. Vaccaro. Isolute Si-carbonate catalyzes the
nitronate addition to both aldehydes and electron-poor alkenes under solvent-free conditions.
Green Chem. 2008, 10, 541-544.
G. Bellachioma, L. Castrica, F. Fringuelli, F. Pizzo*, and L. Vaccaro*. Catalyst- and solventfree conditions as an environmentally benign approach to 4-aryl-3-cyano-hexahydro-4H-1,2benzoxazine-2-oxides. Green Chem., 2008, 10, 335–340.
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L. Vaccaro, S. Bonollo, F. Fringuelli, F. Pizzo. L. Vaccaro*. Zr(DS)4 as an Efficient Catalyst
for the Aminolysis of Epoxides in Water. 2007, Synlett, 2683-2686, ISSN: 0936-5214
R. Ballini, L. Barboni, F. Fringuelli, A. Palmieri, F. Pizzo, L. Vaccaro. Recent developments
on the chemistry of aliphatic nitrocompounds under aqueous medium. Green Chem. 2007, 9,
823-838.
F. Fringuelli, O. Piermatti, F. Pizzo, L. Vaccaro. Pericyclic Reactions in Aqueous Media In:
LINDSTROM U. MARCUS. Organic Reactions in Water. 2007, 146-184, OXFORD: Blackwell
Publishing, ISBN: 9781405138901.
L. Castrica, F. Fringuelli, L. Gregoli, F. Pizzo, L. Vaccaro*. Amberlite IRA900N3 as a new
catalyst for the azidation of alpha,beta-unsaturated ketones under solvent-free conditions. J.
Org. Chem, 2006, 71, 9536-9539.
F. Pizzo. F. Fringuelli , O. Piermatti, R. Girotti, L. Vaccaro*. Uncatalyzed and solvent-free
multicomponent process for the synthesis of biphenyl-2-carbonitrile derivatives. Org. Lett.
2006, 8, 5741-5744.
L. Vaccaro*. Catalysis in unconventional media. Towards a Green Synthesis of Target
Molecules. LATV. KIM. ZUR. 2006, 1, 41-47.
S. Bonollo, F. Fringuelli, F. Pizzo, L. Vaccaro*. A green route to ß-amino alcohols via the
uncatalyzed aminolysis of 1,2-epoxides by alkyl- and arylamines. Green Chem. 2006, 8, 960964.
F. Fringuelli, R. Girotti, F. Pizzo, L. Vaccaro. [AlCl3+2THF]: a new and efficient catalytic
system for Diels-Alder cycloaddition of a,ß-unsaturated carbonyl compounds under solventfree condition. Org. Lett. 2006, 8, 2487-2489.
F. Fringuelli, F. Pizzo, C. Vittoriani, L. Vaccaro*. Polystyrene-Supported 1,5,7Triazabicyclo[4.4.0]dec-5-ene as an Efficient and Reusable Catalyst for the Thiolysis of 1,2Epoxides under Solvent-Free Conditions. Eur. J. Org. Chem. 2006, p. 1231-1236.
F. Fringuelli, F. Pizzo, S. Tortoioli, C. Zuccaccia, L. Vaccaro*. In(OTf)3-catalyzed thiolysis of
1,2-epoxides by arylthiols under SFC. A new approach for the synthesis of thiazolopyridinium
ionic liquids. Green Chem. 2006, 8, 191-196.
F. Fringuelli, R. Girotti, F. Pizzo, E. Zunino, L. Vaccaro* Hafnium Chloride Tetrahydrofuran
Complex Catalyzed Diels-Alder Cycloadditions of 3-Ethoxycarbonylcoumarins with 1,3Dienes under Solvent-Free Conditions. Adv. Synth. Catal. 2005, 348, 297-300.
R. Girotti, A. Marrocchi, L. Minuti, O. Piermatti, F. Pizzo, L. Vaccaro. Diels-Alder Reactions
of 3-Substituted Coumarins in Water and under High-Pressure Condition. An Uncatalyzed
Route to Tetrahydro-6H-benzo[c]chromen-6-ones. J. Org. Chem. 2005, 71, 70-74.
G. D'Ambrosio, F. Fringuelli, F. Pizzo, L. Vaccaro*. TBAF-Catalyzed [3+2] Cycloaddition of
TMSN3 to 3-Nitrocoumarins Under SFC: an Efficient Green Route to Chromeno [3,4-d]
[1,2,3] triazol-4(3H)-ones. Green Chem., 2005, 7, 874-877.
F. Fringuelli, F. Pizzo, S. Tortoioli, L. Vaccaro*. InCl3-Catalyzed Regio- and Stereoselective
Thiolysis of alpha,beta-Epoxycarboxylic Acids in Water.Org. Lett. 2005, 7, 4411-4414.
D. Amantini, F. Fringuelli, O. Piermatti, F. Pizzo, E. Zunino, L. Vaccaro*. Synthesis of 4-Aryl1H-1,2,3-Triazoles Through TBAF-Catalyzed [3+2] Cycloaddition of 2-Aryl-1-nitroethenes
with TMSN3 under Solvent-Free Conditions. J. Org. Chem., 2005, 70, 6526-6529.
F. Fringuelli, F. Pizzo, S. Tortoioli, L. Vaccaro*. Thiolysis of 1,2-Epoxides Under
Environmental Friendly Conditions. In: VARIOUS AUTHORS. Targets in Heterocyclic
Systems Chemistry and Properties. vol. 8, p. 146-161, ROMA: 2005, ISBN: 978888620829.
F. Fringuelli, F. Pizzo, S. Tortoioli, L. Vaccaro*. One-Pot Synthesis of Benzo[e]1,4oxathiepin-5-ones under Solvent Free Condition via Self-Promoted Thiolysis of 1,2-Epoxides.
J. Org. Chem. 2004, 69, 8780-8785.
F. Fringuelli, F. Pizzo, C. Vittoriani, L. Vaccaro*.Polystyril-supported TBD As an Efficient and
Reusable Catalyst Under Solvent-Free Conditions. Chem. Commun., 2004, 2756-2757.
F. Fringuelli, F. Pizzo, S. Tortoioli, L. Vaccaro*. Solvent-Free Al(OTf)3-Catalyzed Aminolysis
of 1,2-Epoxides by 2-Picolylamine: A Key Step in the Synthesis of Ionic Liquids. J. Org.
Chem. 2004, 69, 7745-7747.
D. Amantini, R. beleggia, F. Fringuelli, F. Pizzo, L. Vaccaro. TBAF-Catalyzed Synthesis of 5Substituted 1H-Tetrazoles under Solventless Conditions. J. Org. Chem. 2004, 69, 28962898, ISSN: 0022-3263
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F. Fringuelli, F. Pizzo, L. Vaccaro*. NaOH-Catalyzed Thiolysis of alpha,beta-Epoxyketones
in Water. A Key Step in the Synthesis of Target Molecules Starting from alpha,betaUnsaturated Ketones. J. Org. Chem. 2004, 69, 2315-2321.
D. Amantini, F. Fringuelli, F. Pizzo, S. Tortoioli, L. Vaccaro*. ZnCI2 as an Efficient Catalyst
in the Thiolysis of 1,2-Epoxides by Thiophenol in Aqueous Medium. Synlett 2003, 22922296.
D. Amantini, F. Fringuelli, O. Piermatti, F. Pizzo, L. Vaccaro. 3-Nitrocoumarins as
Dienophiles in the Diels-Alder Reaction in Water. An Approach to the Synthesis of
Nitrotetrahydrobenzo[c]chromenones and Dihydrodibenzo[b,d]furans J. Org. Chem. 2003,
68, 9263-9268.
F. Fringuelli, F. Pizzo, S. Tortoioli, L. Vaccaro*. Zn(II)-Catalyzed Thiolysis of Oxiranes in
Water under Neutral Conditions. Fringuelli, F.; Pizzo, F.; Tortoioli, S.; Vaccaro, L. J. Org.
Chem. 2003, 68, 8248-8251.
F. Fringuelli, F. Pizzo, S. Tortoioli, L. Vaccaro. Thiolysis of 1,2-Epoxides by Thiophenol
Catalyzed Under Solvent-Free Conditions. Tetrahedron Lett. 2003, 44, 6785-6787.
F. Fringuelli, F. Pizzo, M. Rucci, L. Vaccaro*. First One-Pot Copper-Catalyzed Synthesis of
alpha-Hydroxy-beta-Amino Acids in Water. A New Protocol for the Preparation of Optically
Active Norstatines J. Org. Chem. 2003, 68, 7041-7045.
F. Fringuelli, O. Piermatti, F. Pizzo, L. Vaccaro. Indium Salts-Promoted Organic Reactions.
Curr. Org. Chem. 2003, 7, 1661-1689.
D. Amantini, F. Fringuelli, F. Pizzo, O. Piermatti, L. Vaccaro*. Environmentally-Friendly
Synthesis and Reactions of alpha,beta-Unsaturated Nitroalkenes . In: R. SANGHY AND
M.M. SRIVASTAVA. Green Chemistry: Environmental Friendly Alternatives. 2003, 167-190,
New Delhi:Narosa Pb. House, ISBN: 9788173195235
F. Fringuelli, F. Pizzo, S. Tortoioli, L. Vaccaro. Easy and Environmentally Friendly
Uncatalyzed Synthesis of beta-Hydroxy Arylsulfides by Thiolysis of 1,2-Epoxides in Water.
Green Chem., 2003, 5, 425-428.
G. Fioroni, F. Fringuelli, F: Pizzo, L. Epoxidation of alpha,beta-Unsaturated Ketones inWater.
An Environmentally Benign Protocol. Green Chem., 2003, 5, 436-440.
D. Amantini, F. Fringuelli, O. Piermatti, S. Tortoioli, L. Vaccaro. Nucleophilic Ring Opening of
1,2-Epoxides in Aqueous Medium. ARKIVOC, 2002, p. 293-311.
F. Fringuelli, F. Pizzo, S. Tortoioli, L. Vaccaro. Thiolysis of Alkyl-and Aryl-1,2-Epoxides in
Water Catalyzed by InCl3. Adv. Synth. Catal., 2002, 344, 379-384.
D. Amantini, F. Fringuelli, F. Pizzo, L. Vaccaro L. (Selected Methods for the Reduction of the
Azido Group. Org. Prep. Proc. Int. , 2002, 34, 109-147.
D. Amantini, F. Fringuelli, O. Piermatti, F. Pizzo, L. Vaccaro. Water, a clean, inexpensive,
and re-usable reaction medium. One-pot synthesis of (E)-2-aryl-1-cyano-1-nitroethenes.
Green Chem., 2001, 3, 229-232.
D. Amantini, F. Fringuelli, F. Pizzo, L. Vaccaro. Efficient O-Trimethylsilylation of Alcohols
and Phenols With Trimethyilsilylazide Catalyzed by Tetrabutylammonium Bromide Under
Neat Conditions . J. Org. Chem., 2001, 66, 6734-6727.
F. Fringuelli, F. Pizzo, L. Vaccaro. Lewis-Acid Catalyzed Organic Reactions in Water. The
Case of AlCl3, TiCl4 and SnCl4 Belived to be Unusable in Aqueous Medium. J. Org. Chem.
2001, 66, 4719-4722.
D. Amantini, F. Fringuelli, F. Pizzo, L. Vaccaro. Bromolysis and Iodolysis of a,ßEpoxycarboxylic Acids in Water Catalyzed by Indium Halides. J. Org. Chem. 2001, 66, 44634467.
F. Fringuelli, F. Pizzo, L. Vaccaro. Azidolysis of alpha,beta-Epoxycarboxylic Acids. a WaterPromoted Process Efficiently Catalyzed by Indium Trichloride at pH 4.0. J. Org. Chem. 2001,
66, 3554-3558.
F. Fringuelli, F. Pizzo, L. Vaccaro. AlCl3 as an Efficient Lewis Acid Catalyst in water.
Tetrahedron Lett. 2001, 42, 1131-1133.
F. Fringuelli, O., F. Pizzo, L. Vaccaro. Recent Advances in Lewis-Acid Catalyzed Diels-Alder
Reactions in Aqueous Media. Eur. J. Org. Chem. 2001, 439-455.
F. Fringuelli, F. Pizzo, L. Vaccaro. First Efficient Regio- and Stereoselective Metal-Catalyzed
Azidolysis of 2,3-Epoxycarboxylic Acids in Water. Synthesis, 2000, 646-650.
118. F. Fringuelli, F. Pizzo, L. Vaccaro. Cobalt(II)Chloride-Catalyzed Chemioselective Sodium
Borohydride Reduction of Azides in Water. Synlett 2000, 311-314.
119. F. Fringuelli, O. Piermatti, F. Pizzo, L. Vaccaro. Ring Opening of Epoxides with Sodium
Azide in Water. A Regioselective pH-Controlled Reaction. J. Org. Chem 1999, 64, 60946096.
8 additional publication are currently under review:
1. M. Alonzi, D. Lanari, S. Santoro, F. Pizzo, L. Vaccaro*. A Peterson-like synthesis of
alkenyl nitriles.
2. G. Strappaveccia, T. Angelini, F. Pizzo, A. Marrocchi, O. Piermatti, L. Vaccaro*.- A
Sustainable and Straightforward Synthesis of β-Cyano Ketones Catalyzed by a
Heterogeneous Fluoride Catalyst.